Observation of the “isomerization” States of Hcp: “isomerization” State vs. “normal- Mode-type” State
نویسندگان
چکیده
Among various kinds of bond-breaking isomerization reactions, the isomerization of a triatomic monohydride, HAB, is the simplest one: HAB ABH. This system is most fundamental for both experimental and theoretical studies. On the basis of a time-independent picture, the isomerization process can be characterized by analysis of rotation-vibration eigenstates in the high energy region. In this study, highly excited vibrational states of HCP were investigated by dispersed fluorescence and stimulated emission pumping spectroscopies. As a result, two distinct families of vibrational states were observed in the 1340
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